Part 3:
Values We Infer


While temperature, humidity, pressure, and wind data tell us much about current atmospheric conditions, in and of themselves, they tell us little about future conditions. We can use them, however, to determine the values of other parameters which are necessary for forecasting and modeling the atmosphere. Computers now calculate these values for us so you will not be expected to make these computations yourself during this course. However, a look at how a few of these parameters are defined either mathematically or graphically can increase your understanding of the behavioral influences of the atmosphere.


Equation of State

A Sample of Water Vapor in Two Different States If we want to model the behavior of the atmosphere, which is mostly made up of gases, we must study the natural behavior of gases. All gases are found to approximate the equation of state. The equation of state does just what its name suggests. It tells us of the state of a particular gas under a broad range of conditions. The equation of state defines the relationship between the temperature (T), density (), and pressure (P) of the gas. These we call the state variables. The equation of state can be written as

P = R T

Pressure = Density x Gas Constant x Temperature

where P is measured in pascals (Pa), is in grams per cubic meter (kg/m3), T is in degrees Kelvin (K), and R is in Joules per kilogram per degree Kelvin (J kg -1 K -1). R is a proportionality constant and is different for each gas or mixture of gases. The inverse of density is called specific volume () and is defined as the amount of volume required for one unit of mass at a given temperature and pressure. Specific volume is commonly expressed as cubic meters of gas per kilogram of gas (m3/kg). By substituting specific volume for density we can rewrite the equation of state as

P = R T

Pressure x Specific Volume = Gas Constant x Temperature

Though the atmosphere is a mixture of gases, atmospheric scientists have discovered that the atmosphere also closely approximates the equation of state. For the dry atmosphere (i.e., no water vapor present) R = 287 Jkg-1K-1. This means that we can take a sample of dry air and measure the initial temperature, pressure, and volume. If we then control one variable and alter another, we can compute the third. The equation of state is a fundamental law governing the behavior of the atmosphere under changing conditions. It allows us to predict temperature, pressure, and density changes in the atmosphere which ultimately determine stability and motion. These, in turn, drive weather systems and transport pollutants.

Computing
with the
Equation of State

This link will provide you with a "pop-up" Javascript calculator that will calculate an unknown variable of the equation of state, given values for the other three variables. Because this calculator is written in Javascript and uses frames, it requires Netscape 2.02 (or a more recent version).


On to Virtual Temperature

Back to Wind

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